High temperature hydrogen attack htha inspectioneering. For corrosion resistant alloys cras there is now pph 2 s low limit, which means precautions need to be taken whenever the possibility of h 2 s is present. Hydrogen induced cracking hic begins with the appearance of the hydrogen blistering on the specimen surface, and cracks generated by the hydrogen blistering gradually extend inward from the surface along the grain boundary, diffuse inside the specimen gradually, and finally form hydrogen induced cracking. The usual physical chemistry of calcocarbonic equilibria is also presented in a new form which better emphasizes the influence of the partial pressure of co 2 as the. High temperature hydrogen attack htha is an insidious condition that can occur in process equipment exposed to hydrogen at elevated temperatures at least 400f or 204c, under dry conditions, when hydrogen disassociates into nascent atomic hydrogen, which is then driven into the steel by the temperature and pressure of the environment. Corrosion testing in co2 and h2s environments lbbc. Effects of h 2 s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels authors wan keun kim dept. High partial pressure h2s pipelines drillernic petroleum 15 apr 05 05. This process is known as hydrogen embrittlement or hydrogeninduced cracking. Pdf the effect of co2 on the permeation of hydrogen in carbon.
Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. When combined these subscripts are applied recursively. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. The effect of the partial pressure of h2s on the permeation of hydrogen in low carbon pipeline steel. The electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and p110 steel were investigated in a simulated acidic annular environment with lowtemperature and high pressure h2s co2 using electrochemical methods, ubend immersion tests, and scanning electron microscopy. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. The formation of subsurface planar cavities, called hydrogen blisters, in a metal. The effect of different partial pressures of h2s ph2sph2s on the hydrogen permeation behaviour of apix52 pipeline carbon steel was investigated in a hightemperature and highpressure hydrogen. The data have been collated and presented on one diagram, and the appropriateness of setting relaxed hardness controls for mildly sour environmental conditions has been discussed. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion. Hydrogeninduced crack growth rate in steel plates exposed to sour environments. Corrosion failures have occurred in unprotected wells and there is some evidence of corrosion despite regular nhibitor treatment.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Processes or conditions involving wet hydrogen sulfide, i. Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. The electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and p110 steel were investigated in a simulated acidic annular environment with lowtemperature and highpressure h2sco2 using electrochemical methods, ubend immersion tests, and scanning electron microscopy. In presence of small amount of h2s, the metal usually fails due to sulfide stress cracking ssc, which is a special type of hydrogen induced cracking hic. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Factors influencing hydrogen induced cracking welding answers. Cracking occurs due to a significant loss in ductility.
Hydrogen cracking its causes, costs and future occurrence. Jul, 20 the presence of electronegative species known to poison hydrogenation recombination reactions on transition metals drastically increases the adsorbed atomic hydrogen uptake. Hic in welding cold cracking haz cracking moisture n org compounds r primary sources of h. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Corrosion and hydrogeninduced cracking of pipeline steel. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang. Abstract h 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. Materials in the sour environment are susceptible to sulfide stress corrosion cracking ssc and hydrogeninduced cracking, hydrogen embrittlement and exfoliation hehic that leads to various modes of failure including stepwise cracking, hence the importance during the design stage on material selection. Cosasco provides hydrogen monitoring solutions for corrosion control such as hydrogen blistering hydrogen induced cracking hic on steel. Influence of hydrogen sulfide on co2 corrosion in pipeline. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Corrosion and hydrogen induced cracking of pipeline steel 1075 this mechanism accounts for the fact that one essential condition for this type of corrosion is direct contact of ss with the metal. Influence of h2s partial pressure on the corrosion behavior.
Introduction hic is a kind of the hydrogen embrittlement which occurs in the form of surface blisters andor internal cracks in the absence of applied stress. However, the test environment of nace tm028496 standard hic. However, the test environment of nace tm028496 standard hic test method is unnecessarily severe than that of actual sour service conditions. Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. The selection of the testing environments for material evaluation or inhibitor performance depends entirely upon the intended. The effect of the partial pressure of h2s and co2 on the permeation of hydrogen in carbon steel by using pressure buildup techniques article pdf available in corrosion houston tx august. Pdf the effect of the partial pressure of h2s and co2 on the. A second problem which sour service can cause in rolled steels, namely hydrogen pressure induced cracking otherwise variously known as hydrogen induced cracking hic, stepwise cracking swc, blister cracking, and by other termshpic, has also been shown to be dependent on hydrogen concentration within the steel, with different steels. When metal is subjected to tensile stress with high level of hydrogen content, hydrogen induced cracking occurs. Sep 07, 2009 the methane molecules create a pressure which leads to embrittlement and even cracking of the metal. The hydrogen induced cracking hic susceptibility of line pipe steel is affected by the hydrogen permeation rate.
For hydrogen induced cracking to take place, individual hydrogen atoms must cluster at the surface of the metal to create hydrogen molecules. It is also called hydrogen assisted cracking hac and delayed cracking since it does not occur right after welding, but a few hours or days after the weld has completely cooled down to ambient temperature. H2s partial pressure, 1 mpa and co2 partial pressure. High temperatures, large chloride content and partial pressure of h2s and small ph make the. Effect of environmental factors on hydrogen permeation in. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. The electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and p110 steel were investigated in a simulated acidic annular environment with lowtemperature and highpressure h2sco2 using electrochemical methods, ubend. The results showed that the peak value of the hydrogen permeation curves, the corrosion rates, the susceptibility to hydrogen induced cracking and the amount of diffusible hydrogen. The hydrogen deleterious effect has a relevant industrial and economic impact being, at the same time, a challenge from the scientific point of view. Over time, the metal becomes so brittle that it cracks. In order to determine the acidity of corrosive media prevailing in oil and gas wells where co 2 corrosion is encountered, a ph meter has been built which enables ph measurements under pressures from 0. Hydrogen induced cracking hic in the oil and gas industry.
Effects of high h2s partial pressure on corrosion of apix52 and x60 pipeline steels were discussed. The effect of different partial pressures of h 2 s p h 2 s on the hydrogen permeation behaviour of apix52 pipeline carbon steel was investigated in a hightemperature and highpressure hydrogen permeation device. Hic test, hydrogen induced cracking test, step wise. Environmental cracking of stainless and nibase alloys hydrogen sulfide corrosion acidic environments hzs as well as co2 can be dissolved in aqueous environments to form acidic, corrosive solutions. O ur last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. Cracking is sometimes accompanied by surface blistering. Blast furnaces give off many unpleasant and unhealthy gases. Particularly common to the oil and gas industry where the use of steel. Naceastm g193 1 includes the following description of hydrogen blistering. All you need to know is these two equations, that stem from one single idea, this idea is called the kinetic theory of gases it assumes that. Effect of pressure on wet h2s co2 corrosion of pipeline steel.
Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen. Effect of h2s partial pressure on stress corrosion. Corrosion and stress corrosion cracking scc tests were performed on the cylinder. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hic test, hydrogen induced cracking test, step wise cracking.
Another condition is the presence of water compare results in fig. The effect of different partial pressures of h 2 s p h 2 s on the hydrogen permeation behaviour of apix52 pipeline carbon steel was investigated in a hightemperature and high pressure hydrogen permeation device. Materials in the sour environment are susceptible to sulfide stress corrosion cracking ssc and hydrogen induced cracking, hydrogen embrittlement and exfoliation hehic that leads to various modes of failure including stepwise cracking, hence the importance during the design stage on material selection. The effects of sulfide stress cracking on the mechanical properties. The results show that the corrosion rate of the two steels increased with the h2s and co2 partial pressure at the temperature of 60oc with a constant h2s co2 partial pressure ratio of 1. Co2 partial pressure 5 to 20 psia most fields in this group used inhibitor batch treatment since startup. Evaluation of the effects of natural gas contaminants on. Hydrogen induced cracking hic on steel for corrosion. Hydrogeninduced crack growth rate in steel plates exposed to. In the solution containing high pressure co2, cr, and p110 steels. Electrochemical and sulfide stress corrosion cracking. The effect of the partial pressure of h2s and co2 on the.
High partial pressure h2s pipelines pipelines, piping and. The co2 partial pressure had no significant effect. Sulfide stress cracking an overview sciencedirect topics. The effect of the partial pressure of h2s and co2 on the permeation of. Hydrogen induced cracking tests of high strength steels. In addition to ph and h2s partial pressure, test duration is another. Effect of pressure on wet h2s co2 corrosion of pipeline. The electrochemical behaviour of two carbon steels exposed to the acidic solutions and their resistance to hydrogen induced cracking hic is evaluated in order to determine the effect of hydrogen damage on the failure process of the steels used in line pipe and casing at a geothermal plant. Corrosion testing in co2 and h2s environments in the oil and gas industry, materials are often exposed to extreme high pressure and temperature conditions and aggressive environments containing chlorides, carbon dioxide co2, hydrogen sulfide h2s and strong acids. Aug 02, 2014 the entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength.
Effect of h2s partial pressure on stress corrosion cracking. The terms stepwise cracking, hydrogen pressure cracking, blister cracking o hydrogen induced stepwise cracking have been used in the past to describe cracking of this type, but are now considered. Preventing hydrogen induced cracking welding answers. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen.
Equivalently, low temperature hydrogen induced cracking was also noticed in inconel 718. H 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. Corrosion and hydrogeninduced cracking of pipeline steel in moist triethylene glycol diluted with liquid hydrogen sulfide. Bai p, zheng s, chen c 2015 electrochemical characteristics of the early corrosion stages of api x52 steel.
It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Influence of h2s partial pressure on the corrosion. Hydrogen induced cracking steel features, applications. Co2 partial pressure under 2 psia no corrosion protection is used with no evidence of downhole corrosion.
Hydrogeninduced crack growth rate in steel plates exposed. Pdf the effect of the partial pressure of h2s and co2 on. High partial pressure h2s pipelines pipelines, piping. Furthermore, the risk of hydrogen induced cracking is present even at partial pressure of h 2 s pph2s below 0.
With three point bend specimens the typical appearance of the sohictype fractures could be reproduced experimentally. Hydrogen induced cracking steel features, applications and. Effect of h2s partial pressure on stress corrosion cracking behavior of cr stainless steel in annulus environment around co2 injection well. This equality arises from the fact that in an ideal gas the molecules are so far apart that they do not interact with each other. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Effects of h2s partial pressure and ph of test solution on. Hydrogen cracking its causes, costs and future occurrence p h m hart weld metal hydrogen cracking in pipeline girth welds, proc.
Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. The rate of x60 was slightly higher than that of x52 steel. The results show that the corrosion rate of the two steels increased with the h2s and co2 partial pressure at the temperature of 60oc with a constant h2sco2 partial pressure ratio of 1. May 19, 2009 susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Corrosion and hydrogeninduced cracking of pipeline steel in. Effects of h2s partial pressure and ph of test solution on the. Factors influencing hydrogen induced cracking welding. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. In addition, hydrogen blistering and hydrogeninduced crack were observed in the x60 steel. The terms stepwise cracking, hydrogen pressure cracking, blister cracking o hydrogeninduced stepwise cracking have been used in the past to describe cracking of this type, but are now considered. Influence of hydrogen sulfide on co2 corrosion in pipeline steel. H2s, co2, sour service, hydrogen embrittlement, sulfide stress cracking, hydrogen induced cracking, high strength steels overview for the first phase of the project solution has been developed to overcome sulfide stress corrosion problems in high strength steel. Corrosionpedia what is hydrogeninduced cracking hic. Unstressed test specimens are exposed to a solution at temperature of.
It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Hydrogeninduced cracking an overview sciencedirect topics. Hydrogen induced cracking hic testing of low alloy steel in sour. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogeninduced cracking also referred to as cold cracking, is caused by the diffusion of hydrogen in the crystal lattice of haz near the fusion boundary. If you recall, we mentioned you need all three factors to be present in order to have hic. H ydrogen induced cracking hic is a far too common type of failure. Daltons law expresses the fact that the total pressure of a mixture of gases is equal to the sum of the partial pressures of the individual gases in the mixture.
The symbol for pressure is usually p or p which may use a subscript to identify the pressure, and gas species are also referred to by subscript. In presence of small amount of h2s, the metal usually fails due to sulfide stress cracking ssc, which is a special type of hydrogeninduced cracking hic. Effect of co2 partial pressure on the corrosion in flow. Hydrogeninduced cracking hic is a far too common type of failure. Hydrogen induced cracking of hard materials zthe refining industry has had very few cases of hydrogen related cracking in pure hydrogen service. Material selection for sour service environment pipeline. Stress corrosion cracking behavior of nickel base alloys. Nayef ma, abdullah aa 2019 the effect of the partial pressure of h 2 s and c o 2 on the permeation of hydrogen in carbon steel by using pressure buildup techniques. Stress corrosion cracking scc of nickelbased alloys. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang dept. A second problem which sour service can cause in rolled steels, namely hydrogen pressure induced cracking otherwise variously known as hydrogeninduced cracking hic, stepwise cracking swc, blister cracking, and by other termshpic, has also been shown to be dependent on hydrogen concentration within the steel, with different steels.
Abstract a mathematical model was proposed for determining the crack growth rate of hydrogen induced cracking hic in steel plates exposed to a sour gas. H2s, co2, sour service, hydrogen embrittlement, sulfide stress cracking, hydrogen induced cracking, high strength steels overview for the first phase of the project solution has been developed to overcome sulfide stress corrosion problems in high strength steel armors in h2s co2 containing environment. We will now go over how to prevent hic from happening. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment.
Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. This clustering produces pressure in the metal which results in the metal losing ductility, toughness and tensile strength. In the gas phase, a stream is sour if the h2s partial pressure exceeds 0. Both sulphide stress corrosion cracking sscc and hydrogen pressure induced cracking hpic have been considered. The effect of the partial pressure of h2s on the permeation. Hydrogen assisted cracking and co2 corrosion behaviors of lowalloy steel with high strength used for armor layer of flexible pipe.
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